A Photochemical and Electrochemical Triggered Bis(hydrazone) Switch
| dc.contributor.author | Gordillo, Mónica A. | |
| dc.contributor.author | Soto-Monsalve, Mónica | |
| dc.contributor.author | Carmona-Vargas, Christian C. | |
| dc.contributor.author | Gutierrez, Gustavo | |
| dc.contributor.author | D'vries, Richard F. | |
| dc.contributor.author | Lehn, Jean-Marie | |
| dc.contributor.author | Chaur, Manuel N. | |
| dc.date.accessioned | 2019-08-05T23:01:06Z | |
| dc.date.available | 2019-08-05T23:01:06Z | |
| dc.date.issued | 2017 | |
| dc.description.abstract | Herein, we report the synthesis of a double hydrazone capable of undergoing photochemical E/Z isomerization through the imine double bonds. The bis(hydrazone) 1-E,E can be considered as a ""two-arm"" system in which the controlled movement of each arm is obtained by photo-modulation, making possible the appearance of two isolable metastable isomeric states 1-E,Z and 1-Z,Z. Such states are characterized by very specific structural, optical and electrochemical properties. The latter, allows the reversible return from either 1-E,Z or 1-Z,Z to the 1-E,E state. Our results are of great importance in the further development of molecular machines and photochemically controlled reactions by introducing for the first time double hydrazones as tunable photochemical switches. | en_US |
| dc.identifier.issn | 1521-3765 | |
| dc.identifier.uri | https://repositorio.usc.edu.co/handle/20.500.12421/482 | |
| dc.language.iso | en | en_US |
| dc.publisher | Chemistry - A European Journal | en_US |
| dc.subject | Bis(hydrazone) | en_US |
| dc.subject | configurational isomers | en_US |
| dc.subject | photoisomerization | en_US |
| dc.subject | supramolecular chemistry | en_US |
| dc.subject | thiopyrimidine | en_US |
| dc.title | A Photochemical and Electrochemical Triggered Bis(hydrazone) Switch | en_US |
| dc.type | Article | en_US |
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