From a planar electrode to a random assembly of microelectrodes: A new approach based on the electrochemical reduction of 5-bromo-1, 10-phenanthroline at gold electrodes

dc.contributor.authorValencia, Drochss P.
dc.contributor.authorR. de Souza, , Ana P.
dc.contributor.authorGonçales, , Vinicius R.
dc.contributor.authorS. Antonio, Jadielson L.
dc.contributor.authorCordoba de Torresi, Susana I.
dc.contributor.authorBertotti, Mauro
dc.date.accessioned2019-08-12T02:37:49Z
dc.date.available2019-08-12T02:37:49Z
dc.date.issued2014
dc.description.abstractA random assembly of microelectrodes (RAMs) was fabricated by electrochemical reduction of 5-bromo-1,10-phenathroline in N,N-dimethylformamide (DMF), generating the 1,10-phenanthroline radical, which was covalently grafted on gold electrodes. After several potential cycles, the gold surface was partially blocked with an insulating film of 1,10-phenanthroline and the resulting modified electrode exhibited the characteristics of a RAMs for the electrochemical reduction of the reversible probe 1,4-benzoquinone in DMF. Scanning electron microscopy and atomic force microscopy were used to examine the morphology of the electrodeposited film and to characterize the existence of micro-regions of gold not coated by the 1,10-phenanthroline film.es
dc.identifier.issn1388-2481
dc.identifier.urihttps://repositorio.usc.edu.co/handle/20.500.12421/563
dc.language.isoenes
dc.publisherElectrochemistry Communicationses
dc.titleFrom a planar electrode to a random assembly of microelectrodes: A new approach based on the electrochemical reduction of 5-bromo-1, 10-phenanthroline at gold electrodeses
dc.typeArticlees

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