1D lanthanide coordination polymers based on lanthanides and 4′-hydroxi-4-biphenylcarboxylic acid: Synthesis, structures and luminescence properties
| dc.contributor.author | D'Vries, Richard F. | |
| dc.contributor.author | Gomez, German E. | |
| dc.contributor.author | Mondragon, Lina Paola | |
| dc.contributor.author | Onna, Diego | |
| dc.contributor.author | Barja, Beatriz C. | |
| dc.contributor.author | Soler Illia, Galo | |
| dc.contributor.author | Ellena, Javier | |
| dc.date.accessioned | 2019-08-05T20:55:05Z | |
| dc.date.available | 2019-08-05T20:55:05Z | |
| dc.date.issued | 2019 | |
| dc.description.abstract | A new family of 1D coordination polymers with formula [Ln(4-OHBBA) 3 (H 2 O) 2 ] and a new 3D supramolecular network topology was obtained. Photoluminescence and sensing tests of doped compounds were performed. Synopsis A family of coordination polymers with formula [Ln(4-OHBBA) 3 (H 2 O) 2 ] with a new 3D supramolecular network topology was obtained. Luminescence properties were studied. Resume A new family of 1D coordination polymers (CPs) based on 4'-hydroxi-4-biphenylcarboxylic acid (4-OHBBA) linker and lanthanide metals were obtained by hydrothermal synthesis. The compounds were fully characterized and present the general formula [Ln(4-OHBBA) 3 (H 2 O) 2 ] (where Ln= La, Pr), crystallizing in the monoclinic P2 1 /c space group. The CPs are formed by "fish bone-like" chains along [010] direction. Also, the topological analysis revels a 3D supramolecular structure with a 7-nodal 3,3,3,4,4,4,4-connected network and the (6.8 2) 2 (6 2 .8) 2 (6 3 .8 2 .10) 2 (6 3) 4 (6 5 .8) 2 (8 6) point symbol. The luminescence and chemical sensing tests of the europium doped compound was performed, finding that the Eu, Tb and Dy-doped samples exhibited dual emissions from the 4-OHBBA ligand and the lanthanide centres. | en_US |
| dc.identifier.issn | 0022-4596 | |
| dc.identifier.uri | https://repositorio.usc.edu.co/handle/20.500.12421/466 | |
| dc.language.iso | en | en_US |
| dc.publisher | Journal of Solid State Chemistry | en_US |
| dc.subject | Coordination Polymers | en_US |
| dc.subject | Luminescence | en_US |
| dc.subject | Lanthanide Metals | en_US |
| dc.subject | Supramolecular Topology | en_US |
| dc.title | 1D lanthanide coordination polymers based on lanthanides and 4′-hydroxi-4-biphenylcarboxylic acid: Synthesis, structures and luminescence properties | en_US |
| dc.type | Article | en_US |
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