Physical-mechanical behavior and water-barrier properties of biopolymers-clay nanocomposites

dc.contributor.authorCalambas, Heidy Lorena
dc.contributor.authorFonseca, Abril
dc.contributor.authorAdames, Dayana
dc.contributor.authorAguirre Loredo, Yaneli
dc.contributor.authorCaicedo, Carolina
dc.date.accessioned2025-07-17T21:43:40Z
dc.date.available2025-07-17T21:43:40Z
dc.date.issued2021
dc.description.abstractThe preparation and characterization of biodegradable films based on starch-PVA-nanoclay by solvent casting are reported in this study. The films were prepared with a relation of 3:2 of starch:PVA and nanoclay (0.5, 1.0, and 1.5% w/v), and glycerol as plasticizer. The nanoclays before being incorporated in the filmogenic solution of starch-PVA were dispersed in two ways: by magnetic stirring and by sonication. The SEM results suggest that the sonication of nanoclay is necessary to reach a good dispersion along the polymeric matrix. FTIR results of films with 1.0 and 1.5% w/v of sonicated nanoclay suggest a strong interaction of hydrogen bond with the polymeric matrix of starch-PVA. However, the properties of WVP, tensile strength, percentage of elongation at break, and Young’s modulus improved to the film with sonicated nanoclay at 0.5% w/v, while in films with 1.0 and 1.5% w/w these properties were even worse than in film without nanoclay. Nanoclay concentrations higher than 1.0 w/v saturate the polymer matrix, affecting the physicochemical properties. Accordingly, the successful incorporation of nanoclays at 0.5% w/v into the matrix starch-PVA suggests that this film is a good candidate for use as biodegradable packaging.
dc.identifier.citationCalambas, H. L., Fonseca, A., Adames, D., Aguirre-Loredo, Y., & Caicedo, C. (2021). Physical-mechanical behavior and water-barrier properties of biopolymers-clay nanocomposites. Molecules, 26(21). https://doi.org/10.3390/MOLECULES26216734
dc.identifier.issn14203049
dc.identifier.urihttps://repositorio.usc.edu.co/handle/20.500.12421/7505
dc.language.isoen
dc.subjectBiodegradable polymers
dc.subjectMechanical properties
dc.subjectMontmorillonite
dc.subjectNanocomposite
dc.subjectUltrasound-assisted
dc.titlePhysical-mechanical behavior and water-barrier properties of biopolymers-clay nanocomposites
dc.typeArticle

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