From waste to raw chemicals: Catalytic transformation of fusel oil by mixed metal oxides

Simple item page
dc.contributor.authorde Lima, Livia Padilha
dc.contributor.authorMora Vargas, Jorge Andrés
dc.contributor.authorRoveda Jr, Antonio Carlos
dc.contributor.authorOrduna Ortega, Julieth
dc.contributor.authorda Silva, Felipe Garcia
dc.contributor.authorCassaro, Rafael Francisco
dc.contributor.authorCardoso, Daniel Rodrigues
dc.contributor.authorBoscolo, Mauricio
dc.contributor.authorMetzker, Gustavo
dc.date.accessioned2025-07-08T21:01:01Z
dc.date.available2025-07-08T21:01:01Z
dc.date.issued2024
dc.description.abstractIn this study, we detail a catalytic process for the conversion of fusel oil (FO), a by-product of ethanol production considered as waste, into valuable organic compounds, including aldehydes, alkenes, ketones, and alkylbenzenes spanning a carbon chain length from C6 to C12. The reaction was carried out in a fixed bed flow reactor at atmospheric pressure, employing mixed metal oxides (MMO) derived from hydrotalcites (HTC) as catalysts. The HTC were readily synthesized by co-precipitation method involving Mg2+ and Al3+, wherein 20 mol% Mg2+ was substituted by M2+ = Mn, Fe, Co, Ni, Cu, and Zn, and MMO obtained by HTC calcination. These catalysts offer cost-effectiveness compared to noble metal-containing ones while exhibiting remarkable activity in dehydrogenation, hydrogenation, and dehydration reactions pivotal for alcohol reactivity. The proposed methodology holds promise for large-scale industrial use and pioneers a fresh avenue for deriving value-added raw chemicals from a renewable carbon source.
dc.identifier.citationde Lima, L. P., Vargas, J. A. M., Roveda, A. C., Ortega, J. O., da Silva, F. G., Cassaro, R. F., Cardoso, D. R., Boscolo, M., & Metzker, G. (2024). From waste to raw chemicals: Catalytic transformation of fusel oil by mixed metal oxides. Applied Catalysis B: Environment and Energy, 351, 123985. https://doi.org/10.1016/J.APCATB.2024.123985
dc.identifier.issn09263373
dc.identifier.urihttps://repositorio.usc.edu.co/handle/20.500.12421/7284
dc.language.isoen
dc.publisherElsevier B.V.
dc.subjectFusel oil
dc.subjectMixed metal oxides
dc.subjectOrganic building blocks
dc.titleFrom waste to raw chemicals: Catalytic transformation of fusel oil by mixed metal oxides
dc.typeArticle

Files

Original bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
From waste to raw chemicals: Catalytic transformation of fusel oil by mixed metal oxides.pdf
Size:
5.84 MB
Format:
Adobe Portable Document Format
Download
License bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
license.txt
Size:
1.71 KB
Format:
Item-specific license agreed upon to submission
Description:
Download

Collections

ArtĂ­culos CientĂ­ficos

Higher Education Institution subject to inspection and surveillance by the Ministry of National Education.
Legal status granted by the Ministry of Justice through Resolution No. 2,800 of September 2, 1959.
Recognized as a University by Decree No. 1297 of 1964 issued by the Ministry of National Education.

Institutionally Accredited in High Quality through Resolution No. 018144 of September 27, 2021, issued by the Ministry of National Education.

Ciudadela Pampalinda

Calle 5 # 62-00 Barrio Pampalinda
PBX: +57 (602) 518 3000
Santiago de Cali, Valle del Cauca
Colombia

Headquarters Centro

Carrera 8 # 8-17 Barrio Santa Rosa
PBX: +57 (602) 518 3000
Santiago de Cali, Valle del Cauca
Colombia

Palmira Section

Carrera 29 # 38-47 Barrio Alfonso LĂ³pez
PBX: +57 (602) 284 4006
Palmira, Valle del Cauca
Colombia

DSpace software copyright © 2002-2025 LYRASIS


Hosting & Support