1D lanthanide coordination polymers based on lanthanides and 4′-hydroxi-4-biphenylcarboxylic acid: Synthesis, structures and luminescence properties

dc.contributor.authorD'Vries, Richard F.
dc.contributor.authorGomez, German E.
dc.contributor.authorMondragon, Lina Paola
dc.contributor.authorOnna, Diego
dc.contributor.authorBarja, Beatriz C.
dc.contributor.authorSoler-Illia, Galo J.A.A.
dc.contributor.authorEllena, Javier
dc.date.accessioned2020-02-09T18:47:30Z
dc.date.available2020-02-09T18:47:30Z
dc.date.issued2019-03-29
dc.description.abstractSynopsis: A family of coordination polymers with formula [Ln(4-OHBBA) 3 (H 2 O) 2 ] with a new 3D supramolecular network topology was obtained. Luminescence properties were studied. Resume: A new family of 1D coordination polymers (CPs) based on 4′-hydroxi-4-biphenylcarboxylic acid (4-OHBBA) linker and lanthanide metals were obtained by hydrothermal synthesis. The compounds were fully characterized and present the general formula [Ln(4-OHBBA) 3 (H 2 O) 2 ] (where Ln = La, Pr), crystallizing in the monoclinic P2 1 /c space group. The CPs are formed by “fish bone-like” chains along [010] direction. Also, the topological analysis revels a 3D supramolecular structure with a 7-nodal 3,3,3,4,4,4,4-connected network and the (6.8 2 ) 2 (6 2 .8) 2 (6 3 .8 2 .10) 2 (6 3 ) 4 (6 5 .8) 2 (8 6 ) point symbol. The luminescence and chemical sensing tests of the europium doped compound was performed, finding that the Eu, Tb and Dy -doped samples exhibited dual emissions from the 4-OHBBA ligand and the lanthanide centreses
dc.identifier.issn00224596
dc.identifier.urihttps://repositorio.usc.edu.co/handle/20.500.12421/2648
dc.language.isoenes
dc.publisherAcademic Press Inc.es
dc.subjectCoordination polymerses
dc.subjectSupramolecular topologyes
dc.subjectLanthanide metalses
dc.subjectLuminescencees
dc.title1D lanthanide coordination polymers based on lanthanides and 4′-hydroxi-4-biphenylcarboxylic acid: Synthesis, structures and luminescence propertieses
dc.typeArticlees

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