1D lanthanide coordination polymers based on lanthanides and 4′-hydroxi-4-biphenylcarboxylic acid: Synthesis, structures and luminescence properties
dc.contributor.author | D'Vries, Richard F. | |
dc.contributor.author | Gomez, German E. | |
dc.contributor.author | Mondragon, Lina Paola | |
dc.contributor.author | Onna, Diego | |
dc.contributor.author | Barja, Beatriz C. | |
dc.contributor.author | Soler-Illia, Galo J.A.A. | |
dc.contributor.author | Ellena, Javier | |
dc.date.accessioned | 2020-02-09T18:47:30Z | |
dc.date.available | 2020-02-09T18:47:30Z | |
dc.date.issued | 2019-03-29 | |
dc.description.abstract | Synopsis: A family of coordination polymers with formula [Ln(4-OHBBA) 3 (H 2 O) 2 ] with a new 3D supramolecular network topology was obtained. Luminescence properties were studied. Resume: A new family of 1D coordination polymers (CPs) based on 4′-hydroxi-4-biphenylcarboxylic acid (4-OHBBA) linker and lanthanide metals were obtained by hydrothermal synthesis. The compounds were fully characterized and present the general formula [Ln(4-OHBBA) 3 (H 2 O) 2 ] (where Ln = La, Pr), crystallizing in the monoclinic P2 1 /c space group. The CPs are formed by “fish bone-like” chains along [010] direction. Also, the topological analysis revels a 3D supramolecular structure with a 7-nodal 3,3,3,4,4,4,4-connected network and the (6.8 2 ) 2 (6 2 .8) 2 (6 3 .8 2 .10) 2 (6 3 ) 4 (6 5 .8) 2 (8 6 ) point symbol. The luminescence and chemical sensing tests of the europium doped compound was performed, finding that the Eu, Tb and Dy -doped samples exhibited dual emissions from the 4-OHBBA ligand and the lanthanide centres | es |
dc.identifier.issn | 00224596 | |
dc.identifier.uri | https://repositorio.usc.edu.co/handle/20.500.12421/2648 | |
dc.language.iso | en | es |
dc.publisher | Academic Press Inc. | es |
dc.subject | Coordination polymers | es |
dc.subject | Supramolecular topology | es |
dc.subject | Lanthanide metals | es |
dc.subject | Luminescence | es |
dc.title | 1D lanthanide coordination polymers based on lanthanides and 4′-hydroxi-4-biphenylcarboxylic acid: Synthesis, structures and luminescence properties | es |
dc.type | Article | es |
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