Synthesis, characterization, and redox potential properties of a new double-stranded Ni-bis(hydrazone)-based helicate
| dc.contributor.author | Villada, Juan D. | |
| dc.contributor.author | Carmona Vargas, Christian C. | |
| dc.contributor.author | Alcides Ellena, Javier | |
| dc.contributor.author | Ayala, Alejandro P. | |
| dc.contributor.author | Ramírez Pradilla, Juan S. | |
| dc.contributor.author | Combariza, M. Y. | |
| dc.contributor.author | Galarza, Esperanza | |
| dc.contributor.author | D'Vries, Richard Fernando | |
| dc.contributor.author | Chaur, Manuel N. | |
| dc.date.accessioned | 2020-10-23T22:57:39Z | |
| dc.date.available | 2020-10-23T22:57:39Z | |
| dc.date.issued | 2020-08-25 | |
| dc.description.abstract | Herein we report the synthesis and structural characterization of a new Ni-bis(hydrazone) complex with the chemical formula [Ni2(L)2(Cl)2](Cl)2·2H2O (L = 2-(heptylthio)-4,6-bis(2-((E)-pyridin-2-ylmethylene)hydrazineyl)pyrimidine). Suitable crystals for X-ray diffraction showed the supramolecular interactions of this complex to exhibit a helical structure coordinating two Ni2+ metal ions bounded by two 2-(heptylthio)-4,6-bis(2-((E)-pyridin-2-ylmethylene)hydrazineyl)pyrimidine ligands. In addition, exploitation of the electrochemical properties by cyclic voltammetry, for this helicate, showed catalyzing ability for the reduction of H+ to H2. | en_US |
| dc.identifier.issn | 0022-4596 | |
| dc.identifier.uri | http://repositorio.usc.edu.co/handle/20.500.12421/4534 | |
| dc.language.iso | en | en_US |
| dc.publisher | Academic Press Inc. | en_US |
| dc.subject | Bis(hydrazones) | en_US |
| dc.subject | Catalyzed hydrogen reduction | en_US |
| dc.subject | Nickel helicates | en_US |
| dc.subject | Supramolecular chemistry | en_US |
| dc.title | Synthesis, characterization, and redox potential properties of a new double-stranded Ni-bis(hydrazone)-based helicate | en_US |
| dc.type | Article | en_US |
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