Browsing by Author "de Lima, Livia Padilha"
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Item Conversion of 1-butanol into High Value-Added Chemicals by Mixed Metal Oxides: The Influence of Co2+, Ni2+, and Zn2+ into Condensed Phase Products Distribution(Springer, 2024) Mora Vargas, Jorge Andrés; de Paula Dias, Rafael Mafra; de Lima, Livia Padilha; Orduña Ortega, Julieth; Boscolo, Mauricio; Metzker, GustavoAbstract: The catalytic transformation of 1-butanol into condensed products by mixed metal oxides, based on Mg2+ and Al3+, containing Co2+, Ni2+, and Zn2+, into ethers, aldehydes, alkenes, ketones, alkylbenzenes, and phenolic compounds is described. The reactions were conducted at 550 and 600 °C, with and without methanol co-feeding. The presence of Co2+, Ni2+, and Zn2+ in the catalyst structure, together with the reaction temperature and methanol co-feeding, allowed the modulation of the yield and selectivity of each class of product. Also, to the best of our knowledge, this is the first time that phenolic compounds were produced from 1-butanol, and due to the nature of the condensed products found, the Robinson annulation was proposed as the reaction mechanism. The methodology herein described uses a renewable carbon source, is greener than the current ones for synthesizing the classes of compounds mentioned earlier, and can be an alternative for raw materials currently obtained exclusively from petroleum. Graphical Abstract: (Figure presented).Item From waste to raw chemicals: Catalytic transformation of fusel oil by mixed metal oxides(Elsevier B.V., 2024) de Lima, Livia Padilha; Mora Vargas, Jorge Andrés; Roveda Jr, Antonio Carlos; Orduna Ortega, Julieth; da Silva, Felipe Garcia; Cassaro, Rafael Francisco; Cardoso, Daniel Rodrigues; Boscolo, Mauricio; Metzker, GustavoIn this study, we detail a catalytic process for the conversion of fusel oil (FO), a by-product of ethanol production considered as waste, into valuable organic compounds, including aldehydes, alkenes, ketones, and alkylbenzenes spanning a carbon chain length from C6 to C12. The reaction was carried out in a fixed bed flow reactor at atmospheric pressure, employing mixed metal oxides (MMO) derived from hydrotalcites (HTC) as catalysts. The HTC were readily synthesized by co-precipitation method involving Mg2+ and Al3+, wherein 20 mol% Mg2+ was substituted by M2+ = Mn, Fe, Co, Ni, Cu, and Zn, and MMO obtained by HTC calcination. These catalysts offer cost-effectiveness compared to noble metal-containing ones while exhibiting remarkable activity in dehydrogenation, hydrogenation, and dehydration reactions pivotal for alcohol reactivity. The proposed methodology holds promise for large-scale industrial use and pioneers a fresh avenue for deriving value-added raw chemicals from a renewable carbon source.